Calcite and aragonite precipitation from seawater solutions of various salinities: Precipitation rates and overgrowth compositions     

Shaojun Zhong  Alfonso Mucci   《Chemical Geology》1989,78(3-4):283-299

The reaction rate and composition of calcite and aragonite overgrowths precipitated from seawater solutions of various salinities (i.e. S=5, 15, 25, 35, 44) were determined at 25°C and 10^−2.5-atm. CO₂ partial pressure using a constant disequilibrium seeded technique. The rate data were fitted to an empirical rate law of the form:

where n is the empirical reaction order; and k is the rate constant. Calcite precipitation rates in seawater solutions do not vary appreciably as a result of salinity variations over the range investigated, while those for aragonite show an increase in going from the higher (i.e. S=35, 44) to the lower (i.e. S=5, 15, 25) salinity range. This study also confirms previously published findings that above a given saturation state (i.e. Ω_c>/2.6) aragonite precipitates more rapidly than calcite at 25°C.

The incorporation of Sr²⁺ in aragonite and Mg²⁺ in calcite overgrowths are independent of the precipitation rate. The partition coefficient of Sr²⁺ in aragonite is approximately equal to unity and is unaffected by salinity variations between 5 and 44. However, the Mg²⁺ partition coefficient in calcite, increases with decreasing salinity of the parent seawater solutions, possibly as a result of variations in the sulfate content of the solutions and solids.

The experimental results were discussed in the context of a number of geological environments.  相似文献   

Approaches to analyse and model changes in impacts: reply to discussions of “How to improve attribution of changes in drought and flood impacts”*     

Heidi Kreibich  Veit Blauhut  Jeroen C. J. H. Aerts  Laurens M. Bouwer  Henny A. J. Van Lanen  Alfonso Mejia 《水文科学杂志》2020,65(3):491-494

ABSTRACT

We thank the authors, Brunella Bonaccorso and Karsten Arnbjerg-Nielsen for their constructive contributions to the discussion about the attribution of changes in drought and flood impacts. We appreciate that they support our opinion, but in particular their additional new ideas on how to better understand changes in impacts. It is great that they challenge us to think a step further on how to foster the collection of long time series of data and how to use these to model and project changes. Here, we elaborate on the possibility to collect time series of data on hazard, exposure, vulnerability and impacts and how these could be used to improve e.g. socio-hydrological models for the development of future risk scenarios.  相似文献   

Organic carbon isotope ratios of recent sediments from coastal lagoons of the Gulf of Mexico,Mexico     

Alfonso V. Botello  Enrique F. Mandelli  Steve Macko  Patrick L. Parker 《Geochimica et cosmochimica acta》1980,44(3):557-559

The stable carbon isotope composition sedimentary organic carbon was determined in the sediments of seven coastal lagoons of the Gulf of Mexico, Mexico. For most of the lagoons the δ¹³C values for sediments ranged from ?20.1 to ?23.9%. Anomalously low values, ?26.8 to 29.3%. were determined in sediments of two of the studied lagoons, probably due to the presence of organic carbon from anthropogenic sources, naturally absent in these environments. The δ¹³C values determined in the tissues of oysters collected at the same time in the different lagoons were very similar to those recorded in the sediments.  相似文献   

Climate‐driven cyclicity in an Early Cretaceous synrift lacustrine series (Aguilón sub‐basin,NE Spain)     

Ana R. Soria  Arsenio Muñoz  Carlos L. Liesa  Aránzazu Luzón  Alfonso Meléndez  M. Nieves Meléndez 《地学学报》2012,24(5):407-416

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The ignored but common nemertine Psammamphiporus elongatus from the Galician beaches (Spain), affected by the Prestige oil spill     

Alfonso Herrera-Bachiller  Pedro García-Corrales  Carmen Roldán  & Juan Junoy 《Marine Ecology》2008,29(S1):43-50

Nemerteans have been recorded in several studies of the sandy beaches, but usually these specimens have been only regarded as members of the Phylum, with no attempt at identification at any taxonomic level. This lack of identification is partly because of the sampling procedures used to collect beach macroinfauna. Nemerteans are fragile and need special care. They must be isolated and observed in vivo before using histological procedures, which must be employed for the taxonomical studies. This study deals with a sandy beach hoplonemertean, Psammamphiporus elongatus ( Stephenson 1911 ), only known for seven specimens from the Firth of Clyde (UK). This species is recorded for the first time from the Galician sandy beaches (NW Spain) where it reaches its maximum abundance. The species is described and illustrated and new data on its morphology and ecology are provided. The species was apparently affected by the 'Prestige' oil spill, and would be a good indicator of beach quality.  相似文献   

Interannual variability patterns of the world’s total column water content: Amazon River basin     

Isabella Bordi  Roberto De Bonis  Klaus Fraedrich  Alfonso Sutera 《Theoretical and Applied Climatology》2015,122(3-4):441-455

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Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars     

Alberto G. FAIRÉN  James M. DOHM  Victor R. BAKER  Shane D. THOMPSON  William C. MAHANEY  Kenneth E. HERKENHOFF  J. Alexis P. RODRÍGUEZ  Alfonso F. DAVILA  Dirk SCHULZE‐MAKUCH  M. Ramy EL MAARRY  Esther R. UCEDA  Ricardo AMILS  Hirdy MIYAMOTO  Kyeong J. KIM  Robert C. ANDERSON  Christopher P. McKAY 《Meteoritics & planetary science》2011,46(12):1832-1841

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   

In Memoriam: John W. Morse (1946–2009) Texas A&;M University     

Fred T. Mackenzie  Alfonso Mucci  George W. Luther III 《Aquatic Geochemistry》2010,16(2):219-221

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Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale     

Daniel Paradis  Laurie Tremblay  René Lefebvre  Erwan Gloaguen  Alfonso Rivera  Michel Parent  Jean-Marc Ballard  Yves Michaud  Patrick Brunet 《Environmental Earth Sciences》2014,72(5):1325-1348

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.  相似文献   

Temporal variability of selected dissolved elements in the lower Orinoco River,Venezuela     

Abrahan Mora  Juan A. Alfonso  Luzmila Sánchez  Malvis Calzadilla  Soraya Silva  John J. LaBrecque  José A. Azócar 《水文研究》2009,23(3):476-485

Monthly analyses of pH, conductance, alkalinity, total suspended solids, dissolved major cations (Na, K, Ca and Mg), and selected dissolved trace elements (Fe, Al, Mn, Cu, Zn and Cr) were conducted on waters of the lower Orinoco River from February 2004 to May 2006. The data show strong seasonal variability. Major cations had maximum concentrations at low water, and were correlated with pH, conductance and alkalinity because of the tributaries coming from the Andean zones, where the weathering of evaporites and carbonate shales controls water chemistry. K concentrations did not show any relation with evaporite weathering, probably because large amounts of K come from the Guayana Shield rivers as a consequence of feldspar weathering. The concentrations of dissolved Fe, Mn and Cu were highest during the high water stage. Concentrations of the elements K, Cr, Zn and Cu are correlated with each other but not with dissolved Fe and Al, which probably are complexed with humic and fulvic substances. Mn concentrations did not show relationships with other variables. Inter‐annual variability of dissolved elements is explained by temporal changes in precipitation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献